Spray it with a little WD-40 or PB Blaster first, then put the nut back on it and give it a couple whacks with a hammer if you don't have a brass drift or a punch that will fit the end of it without ruining the threads. It should pop loose as it is just a tapered pin put in from the top.
If you want a little more advice, you will find this to be a much easier job if you were to remove the whole strut and control arm assembly and work on it on a workbench, rather than trying to do it while it is still on the car.
Before you try to remove the spindle pin, you ought to soak it with penetrating fluid for a day on both ends and through the locking pin hole.
If you have trouble, use the search function here as there are many, many threads on this job and quite a few options for removing the spindle pin.![]()
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